FILLED PHOTOPOLYMER COMPOSITIONS FOR 3D PRINTING BY STEREOLITOGRAPHY METHOD (OVERVIEW)

UDC 655.225.6:773.92:004.925.84

  • Khodzer Viktoryia Baguslavauna – Master’s degree student, the Department of Mechanics and Engineering. Belarusian State Technological University (13a, Sverdlova str., 220006, Minsk, Republic of Belarus). E-mail: vh58998673194@gmail.com

  • Kordikova Elena Ivanovna – PhD (Engineering), Associate Professor, Assistant Professor, the Department of Mechanics and Engineering. Belarusian State Technological University (13a, Sverdlova str., 220006, Minsk, Republic of Belarus). E-mail:kordikova@tut.by

  • Дьякова Галина Николаевна – ассистент кафедры механики и конструирования. Белорусский государственный технологический университет (220006, г. Минск, ул. Свердлова, 13а, Республика Беларусь). E-mail: kravchenyagn1994@gmail.com

  • Dyakova Halina Nikolaevna – Assistant, the Department of Mechanics and Engineering. Belarusian State Technological University (13a, Sverdlova str., 220006, Minsk, Republic of Belarus). E-mail: aspirantura.bgtu@tut.by

Key words: 3D printing, photopolymer resin, composition, filler, photopolymer printing, stereolithography.

For citation: Khoder V. B., Kordikova E. I., Dyakova H. N. Filled photopolymer compositions for 3D printing by stereolithography method (overview). Proceedings of BSTU, issue 2, Chemical Engineering, Biotechnologies, Geoecology, 2022, no. 1 (253), pp. 27–32 (In Russian). DOI: https://doi.org/10.52065/2520-2669-2022-253-1-27-32.

Abstract

The article gives a brief description of stereolithography technologies using optical systems using ultraviolet or visible light for curing polymer compositions. The features, advantages and disadvantages of these technologies are shown. The materials used in the printing process based on laser stereolithography are considered – photopolymer compositions based on resins of methacrylic monomers and oligomers, oligoesteracrylates, epoxyacrylates and others. In order to create new materials with a complex of valuable operational properties, fillers are introduced into polymer compositions.

Based on the available information from open sources, the classification and analysis of the main types of fillers used in photopolymer compositions are presented in the work: dispersed – fine fraction powders and microspheres; fibrous – glass, metallic, carbon; crystalline – nanodiamonds. Analysis of data on photopolymer composite compositions used in modern three-dimensional printing shows that fillers are the most important element of the structure and have an extensive set of functions – from a complex forming the physical and mechanical characteristics of finished materials to giving specific physical features. Technical data from manufacturers allow us to analyze the physico – mechanical and technological properties of currently available photopolymer compositions with the addition of dispersed particles of various kinds.

References

  1. Gibson Ya., Rosen D., Stucker B. Tekhnologii additivnogo proizvodstva. Trekhmernaya pechat’, bystroye prototipirovaniye i pryamoye tsifrovoye proizvodstvo [Additive manufacturing technologies. Rapid prototyping to direct digital manufacturing]. Moscow, Tekhnologiya Publ., 2016. 656 p. (In Russian).
  2. Dozhdelev A. M., Lavrentiev A. Yu. Overview of photopolymer materials for 3d printing by stereolitography. Mezhdunarodnyy zhurnal gumanitarnykh i estestvennykh nauk [International Journal of Humanities and Natural Sciences], 2020, no. 9-2 (48), pp. 99–101 (In Russian).
  3. Shkuro A. E., Krivonogov P. S. Tekhnologii i materialy 3D-pechati [Technologies and materials for 3D printing]. Ekaterinburg, Uralsk State Forestry Engineering University Publ., 2017. 101 p. (In Russian).
  4. Industrial 3D-printing materials and resin. Available at: https://www.3dsystems.com/materials (accessed 10.10.2021).
  5. 3D-printing Materials Library. Available at: https://formlabs.com/materials (accessed 10.10.2021).
  6. Ceramic Materials. Available at: https://tethon3d.com (accessed 10.10.2021).
  7. Materiaux d’impression 3d pour applications industrielles. Available at: https://www.prodways.com/fr/material (accessed 10.10.2021).
  8. Ceramic materials. Available at: https://www.lithoz.com/produkte/material (accessed 10.10.2021).
  9. Keramika [Ceramics]. Available at: https://admatec.ru/keramika (accessed 10.10.2021).
  10. Ceramics. Available at: https://3dceram.com/ceramics (accessed 10.10.2021).
  11. Stereolithography. Available at: https://am.covestro.com/en_US/products/stereolithography.html (accessed 10.10.2021).
  12. Resins. Available at: https://monocure3d.com.au/product-category/resins (accessed 10.10.2021).
  13. Resins. Available at: https://www.esun3d.net/products/resins (accessed 10.10.2021).
  14. Produktsiya. Materialy dlya 3D-pechati [Products. Materials for 3D-printing]. Available at: https://harzlabs.com (accessed 10.10.2021).
  15. LCD-resin. Available at: https://www.elegoo.com/collections/resin (accessed 10.10.2021).
  16. Produkty [Pruducts]. Available at: https://funtodo.ru/#products (accessed 10.10.2021).
  17. Chen Z., Li D., Zhou W., Wang L. Curing characteristics of ceramic stereolithography for an aqueous-based silica suspension. Journal of Engineering Manufacture, 2010, Part B, pp. 641–651.
  18. Bondaletova L. I., Bondaletov V. G. Polimernyye kompozitsionnyye materialy (chast’ 1) [Polymer composite materials (part 1)]. Tomsk, Tomsk Polytechnic University Publ., 2013. 118 p. (In Russian).
  19. Griffith M. L. Stereolithography of ceramics: Cand. Thesis. Candidate of those. sciences. Ann Arbor, Michigan, 1995. 86 p.
  20. Miao W., Holloran J. W., Bray D. I. Suspension Polymerization, Casting, Zirconate, Lead, Titanate. Part I: Acrylamide Hydrogel System. Journal of Materials Science, 2003, June, pp. 2571–2579.
  21. Dufo O., Belt S. Stereolithography of PZT ceramic suspensions. Rapid Prototyping Journal, 2002, vol. 8, issue 2, pp. 83–90.
  22. Neo 3D printer series materials. Available at: https://www.stratasys.com/materials/search/neo-3dprinter-series-materials (accessed 10.10.2021).
  23. Krolewski K., Wieloszynska A., Kaminska A., Kardaez K. Optical properties of daylight curable resin doped with nanodiamond powder. Photonics letters of Poland, 2019, vol. 11 (3), pp. 81–83.
  24. Quanyi M., Lei W., Conner K. D. Digital light processing 3D printing of conductive complex structures. Additive Manufacturing, 2017, vol. 18, pp. 74–83.
10.11.2021