DEVELOPMENT OF CALCIUM PHOSPHATE COMPOSITIONS FOR 3D PRINTING OF CERAMICS

UDC 666.6

  • Shymanskaya Hanna Mikalaeuna – PhD (Engineering), Assistant Lecturer, the Department of Glass and Ceramics Technology. Belarusian State Technological University (13a, Sverdlova str., 220006, Minsk, Republic of Belarus). E-mail: shimanskaya@belstu.by

  • Popov Rostislav Yurʼevich – PhD (Engineering), Assistant Professor, the Department of Glass and Ceramics Technology. Belarusian State Technological University (13a, Sverdlova str., 220006, Minsk, Republic of Belarus). E-mail: rospopov@mail.ru

  • Pantsialeyenka Fedor Ivanovich – DSc (Engineering), Professor, the Department of Powder Metallurgy, Welding and Materials Technology, NAS Corresponding Member, Honoured Scientist of the Republic of Belarus. Belarusian National Technical University (24, build. 7, Ya. Kolasa str., 220013, Minsk, Republic of Belarus). E-mail: panteleenkofi@mail.ru

  • Podsosonnaya Alexandra Dmitrievna – Masterʼs degree student, the Department of Glass and Ceramics Technology. Belarusian State Technological University (13a, Sverdlova str., 220006, Minsk, Republic of Belarus). E-mail: pod.sosna@inbox.ru

  • Baihazin Dzmitry Alyaksandravich – student. Belarusian State Technological University (13a, Sverdlova str., 220006, Minsk, Republic of Belarus). E-mail: baigazin.dima@mail.ru

  • Pospelov Andrey Vladimirovich – Junior Researcher, the Center for Physical and Chemical Research Methods. Belarusian State Technological University (13a, Sverdlova str., 220006, Minsk, Republic of Belarus). E-mail: Andrei29088@mail.ru

DOI: https://doi.org/10.52065/2520-2669-2021-247-2-187-198

Key words: liquid-phase synthesis, hydroxyapatite, 3D printing, dynamic viscosity, structure.

For citation: Shymanskaya H. M., Popov R. Yu., Pantsialeyenka F. I., Podsosonnaya A. D., Baihazin D. A., Pospelov A. V. Development of calcium phosphate compositions for 3D printing of ceramics. Proceedings of BSTU, issue 2, Chemical Engineering, Biotechnologies, Geoecology, 2021, no. 2 (247), pp. 187–198 (In Russian). DOI: https://doi.org/10.52065/2520-2669-2021-247-2-187-198.

Abstract

Creation of personalized structures for bone tissue engineering based on calcium phosphates using 3D printing methods is one of the promising directions in the development of additive technologies. In this work, a comprehensive study of the influence of the liquid-phase synthesis parameters of hydroxyapatite (pH of the reaction medium, temperature, the duration of holding the precipitate in the mother liquor, subjecting of the mother liquor with the precipitate to microwave irradiation) on the phase composition and particle size distribution of the obtained powder, features of it structure have been carried out. As a result, the optimal conditions have been chosen for the synthesis of hydroxyapatite: pH 10, temperature 60°C, subjecting of the mother liquor with the precipitate to microwave irradiation (700 W, 30 min). For the molding of ceramics the design of a 3D printer have been developed and the experimental 3D printer have been assembled. The technological properties of ceramic masses suitable for 3D printing have been determined: dynamic viscosity – 20,000–60,000 mPa·s; pH 7–8; moisture content – 54– 60 wt. %, and when using binding additives – 70 wt. %. Using differential scanning calorimetry, the temperature-time firing parameters of ceramics on the base of synthesized hydroxyapatite have been determined. The relationship between the composition of ceramics, technological parameters of production, structural features and physico-chemical properties of calcium phosphate materials has been revealed.

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