EFFECT OF MINERALIZING ADDITIVES ON THE SYNTHESIS OF CORUNDUM CERAMICS

UDC 666.3.017

  • Popov Rostislav Yurʼevich – PhD (Engineering), Assistant Professor, the Department of Glass and Ceramics Technology. Belarusian State Technological University (13a, Sverdlova str., 220006, Minsk, Republic of Belarus). E-mail: rospopov@mail.ru

  • Pantsialeyenka Fedor Ivanovich – DSc (Engineering), Professor, the Department of Powder Metallurgy, Welding and Materials Technology, NAS Corresponding Member, Honoured Scientist of the Republic of Belarus. Belarusian National Technical University (24, build. 7, Ya. Kolasa str., 220013, Minsk, Republic of Belarus). E-mail: panteleenkofi@mail.ru

  • Shymanskaya Hanna Mikalaeuna – PhD (Engineering), assistant lecturer, the Department of Glass and Ceramics Technology. Belarusian State Technological University (13a, Sverdlova str., 220006, Minsk, Republic of Belarus). E-mail: shimanskaya@belstu.by

  • Dyatlova Evgenia Mikhaylovna – PhD (Engineering), Assistant Professor, the Department of Glass and Ceramics Technology. Belarusian State Technological University (13a, Sverdlova str., 220006, Minsk, Republic of Belarus). E-mail: dyatlova@belstu.by

  • Podbolotov Kirill Borisovich – PhD (Engineering), Leading Researcher, Assistant Professor. Physical-technical Institute of the National Academy of Sciences of Belarus (10, Akademika Kuprevicha str., 220141, Minsk, Republic of Belarus). E-mail: kirbor@tut.by

Key words: corundum, mineralizing additive, phase composition, structure, mechanical strength.

For citation: Popov R. Yu., Pantsialeyenka F. I., Shymanskaya H. M., Dyatlova E. M., Podbolotov K. B. Effect of mineralizing additives on the synthesis of corundum ceramics. Proceedings of BSTU, issue 2, Chemical Engineering, Biotechnologies, Geoecology, 2021, no. 2 (247), pp. 72–79 (In Russian). DOI: https://doi.org/10.52065/2520-2669-2021-247-2-72-79.

Abstract

The article presents the results of study of the various mineralizing additives effect on the sintering and phase formation of corundum ceramics. Periclase, titanium and zirconium dioxides, manganese (IV) oxide, dolomite, chalk have been used as mineralizing additives. In addition, a reinforcing component was additionally introduced into the experimental masses – waste of kaolin or carbon fibers. The complex effect of a combination of additives on the properties of corundum ceramics, its structure and phase composition has been studied. It has been established that the introduction of up to 2.5 wt. % MnO2 into ceramic masses, in the presence of an additive of 2.5 wt. % TiO2, promotes an increase in apparent density by 13–15%, bending strength by 18–20% and a decrease in water absorption to 0.9–1.0%, open porosity 1.5–2.0% compared to ceramics containing only one mineralizing additive of titanium dioxide. Additional introduction of the reinforcing component up to 2.5 wt. % (fiber) into the compositions of the experimental masses leads to an increase in the strength characteristics by another 10–12%. The structure and phase composition of the obtained ceramic material have been investigated.

References

  1. Bakunov V. S., Lukin E. S. Special technology features of high-density technical ceramic production. Structure control upon sintering. Steklo i keramika [Glass and Ceramics], 2008, no. 11, pp. 17–21 (In Russian).
  2. Lukin E. S. Modern high-density oxide ceramics with the controlled microstructure. Pt.1. Oxide powder aggregation effect on the ceramics sintering and microstructure. Ogneupory i tekhnicheskaya keramika [Refractories and Industrial Ceramics], 1996, no. 1, pp. 5–14 (In Russian).
  3. Pogrebenkov V. M., Reshetnikov A. A., Vereshchagin V. I. Keramicheskaya massa [Ceramic mass]. Patent RF, no. 2136626, 1999.
  4. Boldin M. S., Sakharov N. V., Shotin S. V., Chuvilʼdeev V. N., Nokhrin A. V., Kotkov D. N., Pisklov A. V. Alumina-based ceramic composites fabricated by spark plasma sintering for tribological applications. Vestnik NNGU [Vestnik of Lobachevsky University of Nizhni Novgorod], 2012, no. 6-1, pp. 32–37 (In Russian).
  5. Garshin A. P., Kulik V. I., Nilov A. S. Friction materials based on fiber-reinforced composites with carbon and ceramic matrix for braking systems. Novyye ogneupory [New refractories], 2008, no. 9, pp. 54‒60 (In Russian).
  6. Murzakova A. R., Valeev I. R., Shayakhmetov U. Sh. Technology of the effective multifunctional ceramic composite materials. Ogneupory i tekhnicheskaya keramika [Refractories and Industrial Ceramics], 2012, no. 1–2, pp. 37–39 (In Russian).
  7. Aung Ch. M., Popova N. A., Lukin E. S. Composite ceramics based on electroplaved corund with evetic additive system Al2O3 – TiO2 – MnO. Uspekhi v khimii i khimicheskoy tekhnologii [Advances in chemistry and chemical technology], 2017, vol. 31, no. 3 (184), pp. 10–12 (In Russian).
  8. Garshin A. P., Kulik V. I., Nilov A. S. Impact-resistant materials based on technical ceramics: the achievements and possibility of their ballistic efficiency increasing. Novyye ogneupory [New refractories], 2016, no. 4, pp. 53–67 (In Russian).
  9. Balkevich V. L. Tekhnicheskaya keramika [Technical ceramics]. Мoscow, Stroyizdat Publ., 1984. 256 p. Matrenin S. V., Ilʼin A. P., Kulyavtseva S. V. Low temperature sintering of corundum powders.
    Izvestiya Tomskogo politekhnicheskogo universiteta. Inzhiniring georesursov [Bulletin of the Tomsk Polytechnic University. Geo Assets Engineering], 2018, vol. 329, no. 2, pp. 127–135 (In Russian).
  10. Pletnev P. M., Nepochatov Yu. K., Malikova E. V., Bogaev A. A. Technology of producing corundum armor ceramics modified with complex additives. Izvestiya Tomskogo politekhnicheskogo universiteta. Inzhiniring georesursov [Bulletin of the Tomsk Polytechnic University. Geo Assets Engineering], 2015, vol. 326, no. 3, pp. 40–49 (In Russian).
  11. Lukin E. S. Modern high-density oxide ceramics with a controlled microstructure. Part 2. Substantiation of principles for the choice of modifying additions effecting the sintering degree of oxide ceramics. Ogneupory i tekhnicheskaya keramika [Refractories and Industrial Ceramics], 1996, no. 4, pp. 2–13 (In Russian).
  12. Makarov N. A. Using of additives forming a liquid phase upon sintering in alumina ceramics technology. Steklo i keramika [Glass and Ceramics], 2003, no. 10, pp. 31–34 (In Russian).
30.04.2021