NEW SOLVENT FOR LOW TEMPERATURE DEPARAFFINIZATION OF OIL RAFFINATES
UDC 665.6
Keywords: oil raffinate, dewaxing, solvent, cyclohexanone, toluene, paraffin, paraffin concentrate.
For citation: Grushova E. I., Al-Razoqi A. A. New solvent for low temperature deparaffinization of oil raffinates. Proceedings of BSTU, issue 2, Chemical Engineering, Biotechnologies, Geoecology, 2021, no. 1 (241), pp. 51–56 (In Russian). DOI: https://doi.org/10.52065/2520-2669-2021-241-1-51-56.
Abstract
The influence of the solvent’s new polar component on the dewaxing process of oil raffinates by the method of extractive crystallization using a cyclohexanone – toluene composition as a solvent was studied. It has been found that when using a new solvent, the separation of the oil raffinate into dewaxed and slack wax is more selective in comparison with the industrial solvent acetone – toluene. As a result, the yield of dewaxing product increases, and the content of solid paraffinic hydrocarbons in the gache increases.
Download
References
- Afanas’yev I. P., Lebedev B. P., Talalayev S. Yu., Ishmurzin A. V. Development of an effective technology for the production of winter diesel fuel. Neftepererabotka i neftekhimiya [Oil refining and petrochemistry], 2014, no. 4, pp. 22–26 (In Russian).
- As’ad A. M., Yeneneh A. M., Obanijesu E. O. Solvent dewaxing of heavy crude oil with methyl ethyl ketone. J. Pet. Environ. Biotechnol., 2015, vol. 6, issue 2, pp. 2–5.
- Gaynullin R. R., Gizyatullin E. T., Solodova N. P., Abdullin A. I. Obtaining low-solidifying oil pro-ducts by dewaxing methods. Vestnik Kazanskogo tekhnologicheskogo universiteta [Bulletin of Kazan Technological University], 2013, vol. 16, no. 10, pp. 257–265 (In Russian).
- Antonov S. A., Kosareva O. A., Zaglyadova S. V., Rudyak K. A., Dogadin O. B. Methods for intensifying the process of solvent dewaxing of oil raw materials. Neftyanoye khozyaystvo [Oil industry], 2017, no. 10, pp. 70–72 (In Russian).
- Lee S. W., Ihm S.-K. Hydroisomerization and hydrocracking over platinum loaded ZSM-23 catalysts in the presence of sulfur and nitrogen compounds for the dewaxing of diesel. Fuel, 2014,
vol. 134, pp. 237–243. - El Naggar A. M. A., Mostafa M. S., Zaky M. T. New trend for the pour point depression of a waxy petroleum fraction with in-situ desulphurization using (O2H & OH) radicals coupled with nanoparticles of titanium compounds. Fuel, 2016, vol. 180, pp. 218–227.
- Gerasimov D. N. Izodeparafinizatsiya neftyanogo syr’ya na platinovykh tseolitsoderzhashchikh katalizatorakh. Dis. kand. tekhn. nauk [Isodewaxing of petroleum feedstock on platinum zeolite-containing catalysts. Cand. Diss.]. Moscow, 2014. 134 p.
- Samedova F. I., Gasanova R. Z., Logmanova S. B., Aliev B. M., Abdullaeva Yu. A., Shakhverdiyeva A. F. Study oil fractions from oil from the Absheron field and their processing. Neftegazovyye tekhnologii [Oil and gas technologies], 2015, no. 7, pp. 51–54 (In Russian).
- Aliyev R. R., Kiseleva T. P., Posokhova O. M., Tselyutina M. I. Catalytic dewaxing: state and prospects. Neftepererabotka i neftekhimiya [Oil refining and petrochemistry], 2016, no. 1, pp. 3–8 (In Russian).
- Zakiyeva R. R., Petrov S. M., Kayukova G. P., Bashkirtseva N. Yu. Obtaining base oils of
III quality group according to API classification from heavy hydrocarbon feedstock using hydrocatalytic processes. Vestnik Kazanskogo tekhnologicheskogo universiteta [Bulletin of Kazan Technological University], 2014, vol. 17, no. 18, pp. 209–212 (In Russian). - Gimatdinov R. R., Fakhrutdinov R. Z. The state of production of base oils in Russia. Vestnik Kazanskogo tekhnologicheskogo universiteta [Bulletin of Kazan Technological University], 2016, vol. 19,
no. 11, pp. 58–63 (In Russian). - Shavaliyev I. O., Belousova O. Yu., Kutepov B. I., Yapayev R. Sh. Improving the process of dewaxing raffinates on the oil industry. Bashkirskiy khimicheskiy zhurnal [Bashkir Chemical Journal], 2016,
vol. 23, no. 2, pp. 66–70 (In Russian). - Kurbatova M. V., Cherentsova M. I., Raskulova T. V., Fereferof M. Yu., Ryabtsov A. Yu. Low temperature dewaxing of oils in presence individual solvent. Vestnik AnGTU [AnSTU Bulletin], 2018,
vol. 1, no. 12, pp. 69–72 (In Russian). - Kapustin V. M., Tonkonogov B. P., Fuks I. G. Tekhnologiya pererabotki nefti. V 4 chactyakh. Ch. 3. Proizvodstvo neftyanykh smazochnykh masel [Oil refining technology. Part 3. Production of petroleum lubricating oils]. Moscow, Khimiya Publ., 2014. 328 p.
- ChemPort.Ru. Available at: http://www.chemport.ru/ (accessed 23.10.2020).
- Dipol’nyye momenty nekotorykh veshchestv [Dipole moments of some substances]. Available at: http://chemanalytica.com/book/novyy_spravochnik_khimika_i_tekhnologa/12_obshchie_svedeniya/6106 (accessed 24.10.2020).
- Karpenko O. V., Grushova E. I. Intensification of the process of separating paraffin wax from crude oil by the method of static crystallization. Trudy BGTU [Proceedings of BSTU], 2016, no. 4: Chemistry, Organic Substances Technology and Biotechnology, pp. 54–58 (In Russian).
- Grushova E. I., Al-Razoqi A. A., Karpenko O. V., Alrashedi A. R., Poleshko A. V. Solvent for dewaxing raffinates extracted from distillate oil. Trudy BGTU [Proceedings of BSTU], issue 2, Chemical Engineering, Biotechnologies, Geoecology, 2017, no. 2, pp. 60–63 (In Russian).
- Ivanova P. V., Safiyeva R. Z., Kamelev V. N. IR spectrometry in the analysis of oil and oil products. Vestnik Bashkirskogo universiteta [Bulletin of the Bashkir University], 2008, vol. 13, no. 4, pp. 869–874
(In Russian). - Samedova F. I., Nadzhafova M. A., Akhmedbekova S. F., Abdullayeva Yu. A., Shakhverdiyeva A. F. Study of the compositions and properties of Absheron oil field and its residuals fractions. AvtoGazoZa-pravochnyy kompleks + al’ternativnoye toplivo [Autogas filling complex + alternative fuel], 2015, no. 4 (97), pp. 14–16 (In Russian).
- Grushova E. I., Al-Razoqi A. A., Alrashedi A. R. The effect of cyclohexanol in extraction processes in the production of mineral oils. International Journal of Petroleum and Petrochemical Engineering (IJPPE), 2017, vol. 3, issue 4, pp. 78–80.
- Grushova E. I., Usheva O. A., Al-Razoqi A. A. The use of methyl tert-butyl ether in the extraction processes of refining oil fractions of oil. Trudy BGTU [Proceedings of BSTU], issue 2, Chemical Enginee-ring, Biotechnologies, Geoecology, 2019, no. 1, pp. 32–36 (In Russian).
- Gol’dberg D. O. Kontrol’ proizvodstva masel i parafinov [Control over the production of oils and paraffins]. Moscow, Khimiya Publ., 1964. 120 p.
- Nigmatullin V. R. Sovershenstvovaniye protsessov proizvodstva parafinov i tserezinov i razrabotka matematicheskoy modeli rastvorimosti tverdykh uglevodorodov v keton-aromaticheskikh rastvoritelyakh. Dis. kand. tekhn. nauk [Improving Paraffin and Ceresin Production Processes and Developing a Mathematical Model for Solubility of Solid Hydrocarbons in Ketone-Aromatic Solvents. Cand. Diss]. Ufa, 2000. 128 p.
- Pereverzev A. A., Bogdanov P. F., Roshchin Yu. A. Proizvodstvo parafinov [Paraffin production]. Moscow, Khimiya Publ., 1973. 224 p.
- Nurullayev A. A., Murodov M. N., Sattorov M. O. Studies of the dependence of the properties of petroleum oils on their composition. Nauka i obrazovaniye segodnya [Science and education today], 2016, no. 4 (5), pp. 7–8 (In Russian).