MECHANICAL PROPERTIES AND DURABILITY OF EPOXY COATINGS ON COPPER
UDC 667.6
Keywords: copper coatings, epoxy resin, hardener, hardness, impact strength, durability.
For citation: Prokopchuk N. R., Makarevich O. O., Klyuev A. Yu. Mechanical properties and durability of epoxy coatings on copper. Proceedings of BSTU, issue 2, Chemical Engineering, Biotechnologies, Geoecology, 2021, no. 1 (241), pp. 176–181 (In Russian). DOI: https://doi.org/10.52065/2520-2669-2021-241-1-176-181.
Abstract
The mechanical properties of copper coatings based on epoxy resins ED-20, E-40, KER 828, Etal 245 and experimental hardeners: terpenoid maleic adducts (TDMA) and rosin-terpene maleic adducts (CTMA) were studied. A comparative analysis of the hardness and impact strength of coatings on copper substrates cured with TDMA and KTMA and standard hardeners: polyethylene polyamine (PEPA), triethylenetetramine (TETA) was performed. The influence of the plasticizer on the physical and mechanical properties of coatings has been established. The activation energy of thermo-oxidative destruction of coatings cured with different hardeners is estimated. For the first time, calculations of the durability of coatings were performed using the developed express method.
Download
References
- Skorokhodova O. , Kazakova E. E. Epoxy coatings hardened by adducts. Lakokrasochnye materialy i ikh primeneniye [Paints and varnishes and their application], 1998, no. 6, pp. 3–4 (In Russian).
- Klyuev A. , Skakovskiy E. D. Obtaining rosinterpenemaleic resins from terpentine. Zhurnal prikladnoy khimii [Journal of applied chemistry], 1997, vol. 71, issue 12, pp. 2056–2060 (In Russian).
- Regel V. R., Slutsker A. I., Tomashevsky E. E. Kineticheskaya priroda prochnosti tverdnykh tel [The kinetic nature of the strength of solid bodies]. Moscow, Nauka Publ., 1974. 560 p.
- Prokopchuk N. R. Kineticheskiy printsip prognozirovaniya zavisimosti mekhanicheskikh svoystv polimernykh volokon i plenok ot ikh khimicheskogo stroyeniya i sostava [The kinetic principle of predicting the dependence of the mechanical properties of polymer fibers and films on their chemical structure and composition: abstract of thesis DSc (Chemistry)]. Kiev, 1989, 34 p.
- Emanuel N. M., Bugachenko A. L. Khimicheskaya fizika stareniya i stabilizatsii polimerov [Chemical physics of aging and stabilization of polymers]. Moscow, Nauka Publ., 1988. 360 p.